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題名 | Evaluation of Chemical Equilibrium Constants in Liquid Phase from an Equation of State (Application to the Synthesis of MTBE)=從狀態方程式估計液相之化學平衡常數(MTBE合成上之運用) |
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作者 | Duarte,S. I. Pereira; Pracilio,M. V.; Barreto,G. F.; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
卷期 | 26:6 1995.11[民84.11] |
頁次 | 頁361-369 |
分類號 | 348.45 |
關鍵詞 | 狀態方程式; 液相; 化學平衡常數; Chemical equilibrium constants; MTBE; Generalized equation-of-state; Prediction; |
語文 | 英文(English) |
中文摘要 | 本文提出一估計液相化學平衡常數的方法。其步驟乃利用一個通用的狀態方程式和在標準理想氣體狀態下之各純成分之熱力學數據。也應用這個估計方法來預估MTBE合成反應上之化學平衡常數。結果顯示估計值與一些實驗值相當吻合。文中也討論文獻中一些簡化假設之可議性。 |
英文摘要 | A method to estimate chemical equilibrium constants in liquid phase is presented. The procedure is based on a generalized equation of state and thermodynamic data from pure components at the standard ideal gas state. The method was applied to predict the chemical equilibrium constant for the reaction of MTBE synthesis. A very good agreement was obtained with the available experimental data. The effect of several simplifying hypothesis made in previous contributions is also discussed. |
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