頁籤選單縮合
題名 | Quantification of Coixenolide in Adlay by Measuring 2,3-Butanediol=以測定2,3-丁二醇定量薏仁中薏仁酯 |
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作者 | 陳瑤峰; 張子文; 江文章; | 書刊名 | 食品科學 |
卷期 | 22:5 1995.10[民84.10] |
頁次 | 頁627-636 |
分類號 | 466.17 |
關鍵詞 | 薏仁; 薏仁酯; 轉酯化; 2,3-丁二醇; 反應曲面法; Adlay (Job's tears); Coixenolide; Transesterification; 2,3-butanediol; Response surface methodology; |
語文 | 英文(English) |
中文摘要 | 本研究是將薏仁油進行酸酯化後,利用氣相層析儀把薏仁酯水解產生的2, 3-丁二醇加以定量,然後由2, 3-丁二醇含量換算薏仁酯含量。丙酮比乙醚、正己烷和Folch's溶液能更有效地從糙薏仁中萃出薏仁酯。稱取1g丙酮萃取液溶於20mL7%甲醇-鹽酸溶液後,在100℃沸水浴中迴流4小時。為了避免在減壓濃縮2, 3-丁二醇的損失,濃縮液的最終體積不得少於1 mL。在整個分析過程,2, 3-丁二醇的回收率約93%。利用本法分析臺中選育4號糙薏仁中薏仁酯含量約81ppm。 |
英文摘要 | Coixenolide was quantitatively determined by GC analysis of 2, 3-butanediol, which was liberated from coixenolide by acid-actalyzed transesterification of adlay oil. Acetone was more efficient for the extraction of coixenolide from dehulled adlay than was diethyl ether, n-hexane and folch's solution. One gram of acetone extract was dissolved in 20 mL of 7% methanolic HCI solution (w/w), and the mixture was then refluxed in a water bath at 100℃ for 4 hr. to prevent the loss of 2, 3-butanediol in vacuum concentration, the final volume of the concentrated solution was kept at no less than 1 mL. The recovery of 2, 3-butanediol in the entire analytical procedure was approximately 93%. The coixenolide content of dehulled adlay of Taichung Shuenyu No. 4 was found to be approximately 81 ppm by this method. |
本系統之摘要資訊系依該期刊論文摘要之資訊為主。