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頁籤選單縮合
題 名 | 酵素催化不對稱反應=Enzyme-Catalyzed Asymmetric Reactions |
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作 者 | 林家立; | 書刊名 | 化學 |
卷 期 | 55:1 1997.03[民86.03] |
頁 次 | 頁59-66 |
分類號 | 346.78 |
關鍵詞 | 酵素; 不對稱催化反應; |
語 文 | 中文(Chinese) |
中文摘要 | 近年來,酵素從生物化學領域堂堂步入化學領域,並且蔚成風氣。酵素已成為有 機合成中不可或缺的一份子,其應用在不對稱催化反應上更是方便有效人見人愛。應用酵素 催化的不對稱反應主要有四大類。壹,酵素催化脂、酯、醯、胺、及胼類的水解反應;貳, 酵素催化脂、酯、醯胺、及胼類合成的醯化反應;參;酵素催化的氧化及還原反應;肆,其 化種酵素催化之不對稱反應。這些酵素所催化之不對稱反應在實驗室級的應用上已皆臻健全 ,但在工業級的應用上仍需大家一起努力。 |
英文摘要 | Recently, enzyme has played an important role in chemistry as well as biochemistry. Moreover, enzyme has become an important tool in organic synthesis. It is very convenient for a chemist to apply enzymes in asymmetric reactions. There are four major enzyme-catalyzed asymmetric reactions used in organic synthesis: 1, enzymecatalyzed hydrolyses of lipids, esters, amides, and peptides; 2, enzyme-catalyzed acylations to prepare lipids, esters, amides, and peptides; 3, enzyme-catalyzed oxidations and reductions; 4, other enzyme-catalyzed asymmetric reactions. Now, it is very common to apply enzyme-catalyzed asymmetric reactions in labortary, but not in industry. Therefore, to develop an efficient process to apply enzyme-catalyzed asymmetric reactions in industry becomes an important subject in this field in future. |
本系統中英文摘要資訊取自各篇刊載內容。