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題名 | Correlation of High-Pressure Vapor-Liquid Equilibria for Binary Mixtures Containing CO[feaf]Using Simplified Perturbed Hard Chain Theory=使用簡化之擾動硬鍊理論於含有二氧化碳之雙成份混合物的高壓汽液相平衡研究 |
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作者 | Morotomi,Tatsuo; Sakamoto,Kenji; Hosotani,Noriaki; Iwai,Yoshio; Arai,Yasuhiko; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
卷期 | 27:4 1996.07[民85.07] |
頁次 | 頁235-241 |
分類號 | 348.45 |
關鍵詞 | 擾動硬鍊理論; 二氧化碳; 雙成份混合物; 高壓汽液相平衡; Theory; Perturbed hard chain; Vapor-liquid equilibrium; Supercritical fluid; Carbon dioxide; Hydrocarbon; Alcohol; Citrus oil component; |
語文 | 英文(English) |
英文摘要 | The simplified perturbed hard chain theory (SPHCT) was applied to correlate the high-pressure vapor-liquid equilibria (VLE) of binary mixtures containing supercritical carbon dioxide. The SPHCT has an advantage because no critical property for high-boiling component, which is hardly obtained by experiment, is necessary to determine the characteristic parameters. The three characteristic parameters required in the SPHCT can be estimated by using the effective carbon number (ECN). The VLE of binary systems; CO₂+paraffin, CO₂+aromatic compound, CO₂+alcohol and CO₂+eitrus oil component were studied and the correlation performance of the SPHCT was discussed. |
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