查詢結果分析
相關文獻
- Studies on the Adsorptive Behaviors of Hydrogen on Supported Iridium Catalysts Using Isosteric Heat, the Elovich Equation and TEM
- Surface and Inner Morphology Study of Hydrogenated Amorphous Silicon Films by Electron Microscope Analysis
- cDNA Cloning and Expression Analysis of the Human UDPglucose Dehydrogenase
- 氫氟酸中毒--毒藥物諮詢中心之個案分析
- Partial Hydrogenation of Benzene: A Review
- 半導體工業用矽化氫(Silane)之物性及事故案例
- 應用正交參數設計法備製非晶形矽氫沈積速率之最佳化研究
- 銅及鎘離子對亞鐵離子催化過氧氫分解氯酚類污染物之效應
- 過氧化氫在UV光照射下之裂解行為研究:氯離子及硝酸根離子之影響效應
- 替代燃料對汽柴油引擎性能、毒性、污染與噪音特性分析之研究
頁籤選單縮合
| 題 名 | Studies on the Adsorptive Behaviors of Hydrogen on Supported Iridium Catalysts Using Isosteric Heat, the Elovich Equation and TEM=利用等壓吸附熱、Elovich方程式及穿透式電子顯微鏡研究氫在銥觸媒上的吸附行為 |
|---|---|
| 作 者 | 張聰慧; 陳仕元; 呂芳欽; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
| 卷 期 | 32:1 2001.01[民90.01] |
| 頁 次 | 頁75-80 |
| 分類號 | 468.8 |
| 關鍵詞 | 等壓吸附熱; Elovich方程式; 穿透式電子顯微鏡; 氫; 銥觸媒; Iridium catalyst; Isosteric heat; TEM; Elovich equation; |
| 語 文 | 英文(English) |
| 中文摘要 | 本研究中的銥觸媒係利用初期潤溼法製備,並用等壓吸附熱、穿透式電子顯微鏡及 Elovich方程式來研究氫在還原態的銥觸媒上的吸附行為。研究中發現,當吸附溫度在323K (吸附溫度在273~473K)時,銥觸媒對氫的吸附量達到最大。此現象顯示氫對銥觸媒的吸附在323K以下需要活化能,其值為31~34kJmol¯¹。另外,研究結果也揭示,氫在還原態的銥觸媒上有兩種不同的吸附形態,可能分別吸附在銥觸媒的次表層及表層上,而它們的吸附熱分別為 -65~-40kJmol¯¹及-20kJmol¯¹。 |
| 英文摘要 | Supported iridium catalysts were prepared using the method of incipient wetness by impregnating various supports with a solution of iridium trichloride. The behaviors of hydrogen adsorption on the reduced catalysts were investigated by means of TEM, measurements of the adsorption isotherm in the temperature range of 273~473 K, calculation of the isosteric heat and the activation energy. The maximum capacity of hydrogen adsorption on the supported iridium catalysts appeared at the mid-temperature at 323 K instead of 273 K. This abnormal phenomenon suggested that an activated process was necessary during hydrogen adsorption on the nomenon suggested that an activated process was necessary during hydrogen adsorption on the supported iridium catalysts. The energy barrier of this activated process was calculated to be 31~34 kJ mol¯¹. Furthermore, two types of adsorbed hydrogen with distinct isosteric heat (-65 ~ - 40 kJ mol¯¹ and - 20 kJ mol¯¹) were found through analysis of the hydrogen adsorption isotherms using the Clausius-Clapeyron equation. These two types of adsorbed hydrogen were believed to derive from hydrogen adsorption on the subsurface layer and surface layer of the iridium crystallites, respectively. |
本系統中英文摘要資訊取自各篇刊載內容。