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| 題 名 | Kinetic Study of the Ru(Ⅱ) Catalyzed Oxidation of Pentacyanoferrate(Ⅱ) Complexes by Peroxydisulfate |
|---|---|
| 作 者 | 魏世凱; 葉玉堂; | 書刊名 | Journal of the Chinese Chemical Society |
| 卷 期 | 46:6 1999.12[民88.12] |
| 頁 次 | 頁905-910 |
| 分類號 | 345.85 |
| 關鍵詞 | 催化; 釕; Catalysis; Outer-sphere electron transfer; |
| 語 文 | 英文(English) |
| 英文摘要 | The oxidation reactions of Fe(CN)□L□ (L = 4-ampy, py, dpa) complexes by S□O□ were catalyzed upon the addition of a trace amount of Ru(NH□)□L (L'= pz, py or dcb) complex, and the reaction becomes zeroorder in Fe(II). The reaction time is -10□ fold faster than the simple Fe(CN□)L□-S□O□ system. The mechanism of this Ru(II) catalyzed redox reaction is proposed as Ru(NH□)□L□+ 1/2 S□O□ → Ru(NH□)□L□+SO□ Ru(NH□)□L□+Fe(CN)□L□ □ Ru(NH□)□L□+Fe(CN)□L□ |
本系統中英文摘要資訊取自各篇刊載內容。