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頁籤選單縮合
題名 | A Review Paper on the Kinetic Study of the Pressure-Jump Method=壓力跳躍法於反應動力研究之回顧 |
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作者 | 吳忠信; 林正芳; 駱尚廉; 安永達也; | 書刊名 | Proceedings of the National Science Council : Part A, Physical Science and Engineering |
卷期 | 23:4 1999.07[民88.07] |
頁次 | 頁466-478 |
分類號 | 348 |
關鍵詞 | 壓力跳躍法; 反應動力; Kinetic study; Adsorption; Pressure-jump; |
語文 | 英文(English) |
英文摘要 | Kinetic research often is conducted using tradition methods of kinetic study, namely batch and flow methods. Reaction rate constants and reaction mechanisms, however, are difficult to determine using these methods because too many factors, such as mass-transfer, diffusion, adsorption, and desorption, occur simultaneously in a system. In addition, kinetic information from fast reactions cannot be easily detected. This review paper focuses on the pressure-jump technique, which detects any change in an equilibrium system due to a sudden pressure change, and hence, is able to illustrate the reaction mechanisms and calculate the rate constants. Pressure-jump applications in complex formation, hydrolysis, ion exchange, and adsorption/desorption are discussed in this paper. |
本系統之摘要資訊系依該期刊論文摘要之資訊為主。