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題 名 | 不對稱氫化反應及相關觸媒的發展近況=Recent Progress in Homogeneous Catalytic Asymmetric Hydrogenation Reactions |
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作 者 | 陳新滋; 黃亭棣; 范青華; 白呈超; 李怡靜; | 書刊名 | 化學 |
卷 期 | 55:1 1997.03[民86.03] |
頁 次 | 頁117-142 |
分類號 | 346.01 |
關鍵詞 | 不對稱氫化; 觸媒; 催化; Asymmetric hydrogenation; Homogeneous catalysis; Chiral catalyst; |
語 文 | 中文(Chinese) |
中文摘要 | 本文概述了Ru(BINAP)型觸媒在取代基丙烯酸、酮類、烯胺、不飽和醇類等底物的 不對稱氫化反應中的應用, 並對相關機理、均相 Ru(BINAP) 型觸媒的異相化、溶劑效應等 方面進行了討論。 同時還總結了其它觸媒,如掌性的 Titanocene,掌性氧膦配體等在不對 稱氫化反應中的最近發展。 |
英文摘要 | A review on the recent progress in the studies of the homogeneous catalytic hydrogenation of olefins, ketones, imines, etc. is presented. Particular attention is directed to the studies of the Ru(BINAP) catalyst systems which have been found to be versatile for the asymmetric hydrogenation of a variety of substrates. Detailed mechanistic aspects of each system are discussed. Other novel catalysts such as Rh(Duphos), chiral titanocenes, and Rh(spirOP) have also been found to be of substantial interest. |
本系統中英文摘要資訊取自各篇刊載內容。