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題名 | Preparation and Properties of Acrylonitrile/Maleic Anhydride Graft Poly(vinyl alcohol) Electroconductive Membrane=丙烯腈/馬來酐接枝聚乙烯醇之導電性薄膜的製備與特性 |
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作者 | 江文彥; 郭孟菖 Kuo, Meng-ch'ang; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
卷期 | 27:1 1996.01[民85.01] |
頁次 | 頁25-31 |
分類號 | 467.4 |
關鍵詞 | 丙烯腈; 馬來酐接枝聚乙烯醇; 導電性薄膜; 製程; Graft copolymer; Poly; Vinyl alcohol; Acrylonitrile/maleic anhydride graft copolymer; Electroconductivity; Photoconductivity; Metal chelated film; |
語文 | 英文(English) |
中文摘要 | 本研究乃係合成順丁烯二酐及丙烯腈兩者接枝聚乙烯醇之共聚合物,並將接枝共聚合之產物製成高分子導電薄膜。此種導電性薄膜之製法有二:(1)混合法,(2)浸漬法。經由此二種方法可製得含各種不同金屬鹽之複合薄膜,再經由NaBH₄水溶液還原成含各種不同金屬之金屬化薄膜,用來測其導電性及其他物性。並以 NH₂OH.HCl對PVA-g-AN/MA薄膜上之-CN基進行反應,以導入含amidoxime官能基,以增加薄膜螯合,並推測其可能結構。 |
英文摘要 | Acrylonitrile (AN) and maleic anhydride (MA) were grafted onto PVA to form PVA-g-AN/MA membrane, which was reacted with different metal salts. PVA-g-AN/MA metal chelated films were prepared by the mixing and soaking methods. The electroconductivity of the resulting films was investigated. The amidoxime group was introduced into the PVA-g-AN/MA film under various conditions, in order to increase the amount of ions adsorbed in the soaking method. |
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