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| 題 名 | 庫儲發射藥分解反應動力學參數及爆炸臨界溫度之研究=Research of Decomposition Kinetics Parameters and Explosion Critical Temperatures for the Propellants in Storage |
|---|---|
| 作 者 | 張鐵夫; 李金樹; 陸開泰; 葉早發; | 書刊名 | 中正嶺學報 |
| 卷 期 | 41:1(A) 2012.05[民101.05] |
| 頁 次 | 頁165-176 |
| 分類號 | 595.81 |
| 關鍵詞 | 庫儲發射藥; 動力學參數; 臨界溫度; 熱爆炸延滯時間; Propellant storage; Kinetics parameters; Critical temperature; Delay time of thermal explosion; |
| 語 文 | 中文(Chinese) |
| 中文摘要 | 國軍庫儲大量的發射藥,但除部隊演訓任務外甚少使用,故無法有效推陳換新致紛屆使用壽限或在自然環境下逐漸變質而失去其原有效能。此一數量龐大之發射藥,對國軍官兵及彈庫周遭居民生命及財產安全造成潛在的危機。本研究係針對國軍現有的庫儲發射藥,評估其在熱危害的狀況下儲存的安全性,首先利用熱分析技術探討發射藥的分解反應特性及評估其動力學參數,再利用熱爆炸理論的分析模式,以數值分析的方法,獲得熱爆炸的臨界溫度及延滯時間,研究成果將有助於國軍改善發射藥庫儲的安全管理機制,減少危安事故的發生。 |
| 英文摘要 | The military keeps a huge amount of propellant, but these propellants are seldom used except the period of military maneuvers and training. The propellants of long-term storage cannot be weeded out the old and brought forth the new that can lead to the variation of performance under natural environment or exceed time limit of storage. This potential hazard hangs over the soldiers and the inhabitants in the vicinity. The objective of this research is to evaluate the safety of propellant in the situation of thermal hazard. In the first place, the thermal analysis technique is applied to explore the characteristics of thermal decomposition of propellant and to evaluate the kinetics parameters. Then, the analytic mode of thermal explosion theory is applied to evaluate the critical temperature and delay time of thermal explosion by means of numerical analysis method. The research results will contribute to improving the safety management system of Propellant and reducing the explosive contingency. |
本系統中英文摘要資訊取自各篇刊載內容。