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題 名 | Preparation of cis-Chlorinated Cinnamic Acids by HPLC with a C[feda]Column=以高效液相層析法及C[feda]管柱來純化順式的帶氯肉桂酸 |
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作 者 | 孫芳明; | 書刊名 | 嘉南學報 |
卷 期 | 25 1999.11[民88.11] |
頁 次 | 頁83-89 |
分類號 | 341.393 |
關鍵詞 | 高效液相層析法; C[feda]管柱; 順式; 帶氯肉桂酸; Cis-; Trans-chlorinated cinnamic acids; HPLC; GC-mass; HNMR; Ion-exchange chromatography; |
語 文 | 英文(English) |
中文摘要 | 本研究以一種新式高效液相層析法來分離順式及逆式的帶氯肉桂酸的同分異構 物,由此實驗所得到之順式同分異構物並以氣相質譜儀及一度空間的質子核磁共振光譜來近 一步的做確認分析。由氣相質譜儀及一度空間的質子核磁共振光譜的數據顯示,順式及逆式 的帶氣肉桂酸的質譜及J(對位系數)並不同,因此可以被用於判定此兩個同分異構物之依 據。另外,此實驗所得到之順式同分異構物為純酸,而早期用離子交換樹脂法所得到之順式 帶氯肉桂酸為鈉鹽。因此與用於分離順式及逆式的帶氯肉桂酸的同分異構物的舊的離子交換 樹脂法比較,此一新的高效液相層析法更為簡單、快速及精確。 |
英文摘要 | A HPLC method was developed to separate racemic mixtures of chlorinated cinnamic acids in this study. The cis-isomers obtained by this method were confirmed and characterized by using GC-mass, and one dimensional proton NMR. It was found the resulting data from mass pattern, and the J(coupling constant) for the differences between cis-and trans-chlorinated cinnamic acids can be used as an additional and important index for distinguishing the cis-isomers from the trans-isomers. The obtained cis- isomers by the HPLC method are in the pure acid form. When compared with the cis-isomers (sodium salt) obtained by the ion-exchange chromatography method, the present HPLC method is proved to be simpler, better, and much more precise. |
本系統中英文摘要資訊取自各篇刊載內容。