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題 名 | 官能基型芳磷酯製備=Preparation of Functional Arylphosphate Derivates |
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作 者 | 蘇文烱; | 書刊名 | 新新科技年刊 |
卷 期 | 3 2007.01[民96.01] |
頁 次 | 頁189-199 |
分類號 | 461.6 |
關鍵詞 | 官能基芳磷酯; 合成; 難燃劑; Functional arylphosphate; Preparation; Flame retardant; |
語 文 | 中文(Chinese) |
中文摘要 | 製備含羥基、環氧基或壓克力基的芳磷酯系列化合物,具有高轉化率,高選擇性的製程特點,將酚類化合物、氯化磷醯、催化劑與制酸劑,陸續加入加熱進行三階段酯化反應,經由分子設計提昇產品單體純度;產品經溶於有機溶劑,以少量氨氣去除殘存鹽酸鹽,以無廢水廢物達成純化的目的。 |
英文摘要 | The process for preparing arylphosphate series containing hydroxy、epoxy or acrylic functional group, which has characteristics of high conversion and selectivity, and which comprises o charging sequentially phenolic compounds, phosphoryl chloride, catalyst and organic base, heating the reaction mixture for carring ut a htree stage esterification reaction and improving monor of the product by molecular design. Dissolving the products in organic solvents and removing residual hydrochloride salt with a small amount of ammonia gas, thereby achieving the object of purification without generation of waste water and waste product. |
本系統中英文摘要資訊取自各篇刊載內容。