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題名 | 清潔的低碳烷烴氧化製程=Cleaner Oxidation Process for Light Paraffins |
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作者 | 郭品璽; | 書刊名 | 化工資訊月刊 |
卷期 | 13:5 1999.05[民88.05] |
頁次 | 頁13-21 |
分類號 | 468.8 |
關鍵詞 | 低碳烷烴; 氧化製程; Oxidation process; Light paraffins; |
語文 | 中文(Chinese) |
中文摘要 | 本文介紹三種主要的烷烴選擇性氧化觸媒系統:(1)氧釩焦磷酸鹽,已成功應用 於正丁烷氧化成馬林酸酐製程,此外亦能將正戊烷氧化成馬林酸酐及�本鼯�;(2) 異多體化 合物, 近來倍受矚目, 可以將異丁烷及丙烷氧化成不飽和酸 (甲基丙烯酸及丙烯酸); (3)Rutile 型的混合氧化物,可以當作多種不同金屬元素的載體,以應用於丙烷氨氧化成丙 烯�央C |
英文摘要 | This article describes the reactivity of three catalytic systems having been extensively studied in recent years for the oxidative transformation of light paraffins: (1)Vanadyl pyrophosphate, i.e. the industrial catalyst for the oxidation of n-+butane, (2)Heteropolycompounds, which are currently being studied for the feasibility of oxidating isobutane and propance to the corresponding unsaturated acids (methacrylic acid and acrylic acid), and (3)Rutile-based mixed oxides, which act as the matrix to host various metal components, and have been claimed as optimal catalysts for the ammoxidation of propance to acrylonitrile. |
本系統之摘要資訊系依該期刊論文摘要之資訊為主。