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題名 | Hydrogenolysis of Cyclopropane and Hyderoisomerization of 1-Butene over Zeolite-Supported Ru[feb0](CO)[feba]Catalysts=Ru[feb0](CO)[feba]/ 沸石觸媒之環丙烷加氫分解與1-丁烯加氫異構化反應 |
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作者 | 陳郁文; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
卷期 | 18:3 1987.05[民76.05] |
頁次 | 頁173-178 |
分類號 | 468.8 |
關鍵詞 | 丁烯; 分解; 反應; 沸石; 異構化; 環丙烷加氫; 觸媒; |
語文 | 英文(English) |
中文摘要 | 本研究探討承載上沸石上之Ru₃(CO)[feba]觸媒,對環丙烷加氫分解與1-丁稀加氫異構化反應之催化性質。觸媒係以Ru₃(CO)[feba]蒸氣含量浸製備而成。在環丙烷加氫分解反應中,即使溫度不超過373K,仍會造成金屬聚結。以沸石為擔體之觸媒,其性質遠異於以氧化鋁為擔體之觸媒。以沸石為擔體之觸媒其穩定性亦較佳。 |
英文摘要 | An investigation of the catalytic properties of Ru₃(CO)[feba] supported on NaY for the hydrogenolysis of cyclopane and for the hydro-isomerization of 1-butene has been carried out. The catalysts were prepared via vapor impregnation in a partial vacuum. The hydrogenolysis of cyclopropane over NaY-supported Ru₃(CO)[feba] was found to result in the complete decarbonylation of the carbonyl and also to produce a large amount of sintering of the metal even though the reaction temperature did not exceed 373 K. the zeolite-suported Ru clusters proved to have quite different catalytic proerties from Al₂O₃-supported Ru for the hydrogenolysis of cyclopropane to propane and for the hydroisomerization of 1-butene. In addition, these supported-clusters exhibited greater catalyst stability. |
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