頁籤選單縮合
題 名 | Photochemistry of Methylnitrite (CH[feb0]ONO) in Solid Neon=在固態氖中之甲基亞硝酸鹽的光化學反應 |
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作 者 | 羅文瑞; | 書刊名 | 慈濟技術學院學報 |
卷 期 | 2 2000.08[民89.08] |
頁 次 | 頁115-122 |
分類號 | 346.01 |
關鍵詞 | 固態氖; 甲基亞硝酸鹽; |
語 文 | 英文(English) |
中文摘要 | 以391nm的雷射光照射隔離於7K固態氖中的甲基亞硝酸鹽(CH3ONO),最初產生之光解碎片甲氧基(CH3O)和一氧化氮(NO)會再反應結合生成甲醛(HCHO)和次硝酸(HNO),而非生成原來之甲基亞硝酸鹽(CH3ONO)。所形成穩定的甲醛(HCHO)和次硝酸(HNO)與氣態及固態氬中的實驗結果一致。另外,也量測了甲基亞硝酸鹽(CH3ONO)的紫外吸收光譜。 |
英文摘要 | Methyl nitrite (CH3ONO) isolated in solid neon at 7 K was irradiated with emission from MOPO laser at 391 nm. The photofragments CH3O and NO, formed in primary photodecomposition, recombine to H2CO and HNO, rather than CH3ONO. The stabilization of H2CO and HNO is consistent with gas-phase and in solid argon. In addition the ultraviolet absorption spectrum is also determined. |
本系統中英文摘要資訊取自各篇刊載內容。