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題名 | Kinetics of Anodic Oxidation of 2-Propanol in the Presence of Double Redox Mediator=在氧化還原雙媒子存在下異丙醇進行間接陽極氧化之動力學 |
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作者 | 蔡明瞭; 周澤川; | 書刊名 | 勤益學報 |
卷期 | 14 1996.11[民85.11] |
頁次 | 頁85-103 |
分類號 | 346.01 |
關鍵詞 | 氧化; 還原; 雙媒子; 異丙醇; 陽極氧化; 動力學; |
語文 | 英文(English) |
中文摘要 | 在氧化還原雙媒子存在下異丙醇進行間接陽極氧化之動力研究,結果顯示當NaC1濃度低於3M時,反應速速率與異丙醇濃度呈一級關係,與RuO2和NaC1為零級反應。當NaC1濃度高於3M時,產生鹽析現象,陽極氧化速率受到極大的影響。 |
英文摘要 | The kinetic of anodic oxidation of 2-propanol in the presence of double redox mediators was studied. The results indicated that the reaction rate was first order with respect to 2-propanol and zero order with respect to both ruthenium dioxide and sodium chloride when the concentration of sodium chloride less than 3M. The experimental results correlated with the theoretical analysis ones well. When NaC1 concentration is larger than 3M, the reaction rate mainly depended on the concentrations of both 2-propanol and NaC1 and were first and third orders, respectively, The experimental results could not correlate the theoretical analysis when concentration of NaC1>3M which salting out took place. |
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