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題名 | An Accurate Integral Approximation Formula for Kinetic Analysis of Nonisothermal Data=由非恆溫數據做動力學分析之一準確積分近似式 |
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作者姓名(中文) | 紀榮昌; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
卷期 | 17:3 1986.05[民75.05] |
頁次 | 頁203-207 |
分類號 | 460.02 |
關鍵詞 | 非恆溫; 動力學; 準確; 數據; 積分; |
語文 | 英文(English) |
中文摘要 | 本文推導出一個由非恆溫數據來做動力學分析的新積分近似式。文中並就各種不同的近似法做一比較,結果顯示此新近似式比其它近似式都要準確的多。在整個感興趣的參數範圍內(3.70 E/RT 100.23),此近似式之偏差皆小到可以忽略。當E/RT=3.70時,其偏差為最大;而此最大偏差也只不過是-0.078%而已。此新近似式仍保留其易於做動力學分析之簡單形式。 |
英文摘要 | A new integral approximation formula for kinetic analysis of non-isothermal data is developed. A critical comparison of various approximation methods is made. It is shown that the present approximation is by far the most accurate. Over the entire ranges of parameters of interest (3.70 E/RT 100.23), the deviations for the present approximation are negligibly small. The maximum deviation occurs at E/RT=3.70, and is only -0.078%. The present formula also retains the simple form for easy analysis. |
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