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題 名 | Structures and Magnetic Properties of Two Copper(Ⅱ) Complexes with 2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone Dianionic and Tetrachloroquinone Ligand |
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作 者 | 鍾雲鶴; 方思懿; 方淑慧; 林信宏; 劉勢勇; | 書刊名 | Journal of the Chinese Chemical Society |
卷 期 | 56:6 2009.12[民98.12] |
頁 次 | 頁1099-1107 |
分類號 | 341 |
關鍵詞 | 2,2'-Dipyridylamine; Laccase reaction; Tetrachlorocatechol; Chloranilic acid; 2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone dianionic; Bleaney-Bowers equation; |
語 文 | 英文(English) |
英文摘要 | The polynuclear copper(II) complex [Cu2(Hdpa)2(μ-ClDHBQ)(ClO4)2]n , 1 is bridged by ClDHBQ-2 (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone dianionic ) and 2,2'-dipyridylamine (Hdpa). The other mononuclear complex [Cu(Hdpa)(TeCQ)](DMF), 2, in which tetrachloroquinone (TeCQ) was produced by oxidation of etrachlorocatechol (TeCC), therefore complex 2 is in the quinone form. |
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