頁籤選單縮合
題名 | 含Schiff base配位子鈦錯合物之合成與結構=Preparation and Structures of Titanium(Ⅳ) Complexes Containing Schiff Base Ligand |
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作者 | 陳寶山; 陳彥賢; 王健行; 劉怡新; 何淑華; 曾文峯; | 書刊名 | 大仁學報 |
卷期 | 26 2005.03[民94.03] |
頁次 | 頁1-11 |
分類號 | 345.2 |
關鍵詞 | 子鈦錯合物; 8-hydroxyQuinoline; Triclinic; |
語文 | 中文(Chinese) |
中文摘要 | 當Ti(A1B1)2[A1B12-=N-(2-hydroxylphenyl)salicylideneiminato(2-)]沉澱物生成,溶液為飽和狀態,有利於錯合物Ti(A1B1)Q(OCH3)[HQ=8-hydroxyQuinoline]的產生。在相似的反應有水存在時會生成錯合物[Ti(A1B1)Q]20。新的錯合物[Ti(A1B1)Q]20及Ti(A1B1)Q(OCH3)結晶結構被決定:triclinic,P1(#2),a=7.828(1)Å,b=10.221(1) Å,c=13.547(2) Å,α=111.46(1)0,β=90.37(1)0,γ=105.11(1)0及triclinic,P1(#2),a=10.626(2) Å,b=12.521(4) Å,c=15.851(3) Å,α=76.79(2)0,β=107.48(1)0,γ=103.48(2)0。 |
英文摘要 | Formation Ti(A1B1)Q(OCH3)[HQ=8-hydroxyQuinoline]complex was favorable under the saturated solution when the Ti(A1B1) [A1B12=N-(2-hydroxylphenyl)salicylideneiminato(2-)] precipitate was formed. In a similar reaction condition, [Ti(A1B1)2 O was formed in the presence of water. The crystal structures of the novel Ti(A1B1)Q(OCH3)and [[Ti(A1B1)]2 O were determined : triclinic,P1(#2),a=7.828(1)Å,b=10.221(1) Å,c=13.547(2) Å,α=111.46(1)0,β=90.37(1)0,γ=105.11(1)0及triclinic,P1(#2),a=10.626(2) Å,b=12.521(4) Å,c=15.851(3) Å,α=76.79(2)0,β=107.48(1)0,γ=103.48(2)0. |
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