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題名 | Syntheses and Structures of Zinc(Ⅱ)--Co-ordination Polymers Bridged by Flexible Bidentate Nitrogen Ligands= |
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作者 | 孫茂誠; 吳英彥; 董國忠; 陳志德; 耿台鈞; 王如春; Suen, Maw-cherng; Wu, Ying-yann; Dong, Guo-chung; Chen, Jyh-der; Keng, Tai-chiun; Wang, Ju-chun; |
期刊 | Journal of the Chinese Chemical Society |
出版日期 | 20020600 |
卷期 | 49:3 2002.06[民91.06] |
頁次 | 頁331-334 |
分類號 | 346.01 |
語文 | eng |
關鍵詞 | Supramolecular; Zigzag-chain; Gauche-anti; Self-assembly; |
英文摘要 | The reaction of Zn(NO□)□•6H□O and bpp (bpp=1,3-Bis(4-pyridyl)pronpane) in CH□ OH afforded the complex [Zn(bpp)(NO□)□]□, 1.The IR has been recorded and the structure has been determined. Crystal data for 1: Space group P2(1)/n, a=11.749(1), b=11.41 3(1), c=11.942(1)□, β=96.06(6)°. V=1592.5(3)□, Z-4 with final residuals R1=0.0484 and wR2=0.0984. The complexes show supramolecular structure in the solid state by intermolecular hydrogen bonding interaction. |
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