頁籤選單縮合
題名 | Synthesis of Dienamide Natural Products Using a Hypervalent Iodine(Ⅲ) Reagent |
---|---|
作 者 | 康祐竣; 王惠民; 蘇建興; 陳麟慶; | 書刊名 | 中華藥學雜誌 |
卷期 | 53:4 2001.08[民90.08] |
頁次 | 頁199-205 |
分類號 | 414.33 |
關鍵詞 | Pummerer-type reaction intermediate; Phenyliodine(Ⅲ) bis(trifluoroacetate); Ene reaction; |
語文 | 英文(English) |
英文摘要 | The Pummerer-type reaction intermediate 2 of 1-[(2-methylthio)ethanoyl]- piperidine (1) has been found to react with 1-alkenes to afford ene adducts 3. This methodology has been applied to the synthesis of naturally occurring unsaturated amides N-[(2E,4E)-decadienoyl]piperidine (4d) and N-[(2E,4E)-tetradecadienoyl]piperidine (4g). |
本系統之摘要資訊系依該期刊論文摘要之資訊為主。