頁籤選單縮合
題 名 | Synthesis and Structure Characterization of 2-(Dimethylaminomethyl)pyrrolate and 2,5-Bis(dimethylaminomethyl)pyrrolate Zirconium Complexes |
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作 者 | 黃瑞賢; 郭倍誠; 李錦祥; 彭旭明; | 書刊名 | Journal of the Chinese Chemical Society |
卷 期 | 47:6 2000.12[民89.12] |
頁 次 | 頁1191-1195 |
分類號 | 341.393 |
關鍵詞 | 2-(Dimethylaminomethyl)pyrrolate and 2,5-bis(dimethylaminomethyl)pyrrolate; Zirconium complexes; Pyrrole; Zirconium amide; Metallocene; |
語 文 | 英文(English) |
英文摘要 | Tetrakis(diethylamido)zirconium reacts with 2-(dimethylamino)methyl pyrrole (DMAMP) and 2,5-[bis- (dimethylamino)- methyl]pyrrole (BDMAMP) to give Zr(NEt)2(DMAMP)2 1 and Zr(NEt)3(BDMAMP) 2, respectively. Both 1 and 2 have been characterized by 1H and 13C NMR spectroscopies and 1 has also been characterized by X-ray crystallography. Complex 1 shows an agostic interaction between Zr and H(21A) in solid state that is not sustained in solution. Reacting 1 with 2 equivalents of trimethylsilyl chloride in toluene yields ZrCl2(DMAMP)2 3 in 75% yield which was characterized by 1H and 13C NMR spectroscopies. |
本系統中英文摘要資訊取自各篇刊載內容。