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題名 | 導電性聚苯胺處理紡織品之研究=A Study on the Textiles Treated by Conductive Polyaniline |
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作者 | 徐衛林; 石天威; | 書刊名 | 紡織中心期刊 |
卷期 | 9:1 1999.01[民88.01] |
頁次 | 頁57-66 |
分類號 | 478.1 |
關鍵詞 | 聚酯織物; 聚苯胺; 導電; 電暈; 微波; PET fabric; Polyaniline; Conductive; Corona discharge; |
語文 | 中文(Chinese) |
中文摘要 | 本文以苯胺為原科、過硫酸胺為引發劑,在聚酯織物的纖維表面上,合成導電聚苯胺,研究聚酯織物的電量處理及苯胺單體濃度對織物增重率的影響。並探討不同質子酸,對導電織物掺雜後,織物導電性能的變化。並分析掺雜質子酸,對織物在不同溫度下導電性能的影響。結果表現出,質子酸的耐溫性是影響織物導電耐溫性能的主要因素。而測試導電織物在微波場中吸收微波能量的溫升特性,對照經不同質子酸掺雜後與織物吸收微波能力的差異,結果顯示出織物導電能力與微波的吸收集力成正相關。分析整理後織物FTIR及X-ray等,所反映出的織物內都結構上的變化,通過SEM觀察纖維表面,其結果一致說明聚笨胺在纖微表面,主要是靠物理吸附作用固著在纖維的表面。 |
英文摘要 | In this paper, aniline was copolymerized on the surface of the PET fabric initiated by (NH4)2S2O8,Infleuence of the treatment by corona discharge for the fabric and the influence of the aniline concentration on the fabric's add-on were both discussed. The fabric's conducitvity was analyzed when the fabric treated by polyaniline and then doped by different protonic acid. The conducivity of the treated fabric was affected greatly by temperature, the temperature's influence on the conductivity of the treated fabric doped by Hydroloric acid was analyzed. The thermal behavior of protonic acid can greatly affect the conducitity at different temperature. The temperature rising property of the treated fabric doped by different protonic acids corresponded with the conductivity when the fabric was placed in the microwave irradiation, conductivity affect mostly the fabrics' absorption f the microwave enerygy. the structure of the treated fabric wrer analyzed by FTIR, X-ray and SEM, the results showed that polyaniline was attached tightly on the fiber surface by physical attractoion when the aniline was copolymeriztion on the fiber surface. |
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