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| 題 名 | Measurements of the Heat Capacity and Solid-Liquid Equilibrium of Water-Potassium Chloride and Water-Magnesium Chloride Binary Mixtures=水-氯化鉀及水-氯化鎂系統固液相平衡及比熱的量測 |
|---|---|
| 作 者 | 曾梨子; 陶惟翰; 黃玟蒼; 黃呈加; 陳延平; | 書刊名 | Journal of the Chinese Institute of Chemical Engineers |
| 卷 期 | 33:5 2002.09[民91.09] |
| 頁 次 | 頁469-475 |
| 分類號 | 460.02 |
| 關鍵詞 | 水-氯化鉀及水-氯化鎂; 固液相平衡; 比熱; Solid-liquid equilibrium; DSC; Mathematical model; Heat capacity; |
| 語 文 | 英文(English) |
| 中文摘要 | 本研究利用熱分析儀測量水-氯化鉀和水-氯化鎂之液化溫度以及共晶點溫度。液化溫度對組成之變化圖與文獻值物合。其中水-氯化鉀和水-氯化鎂之共晶組成分別為-11.1℃及-33.2℃。水-氯化鉀的共晶混合物隨時間的加熱曲線,更確定了共晶溫度。水-氯化鉀及水-氯化鎂之共晶組成分別為19.5wt%及21.6wt%的鹽類成份。水-氯化鉀之共晶組成也由共晶分數估算方法來確認。這些極近於共晶組成混合物的固體比熱,也利用熱分析儀數據求得。 |
| 英文摘要 | The eutectic and liquidus temperatures of water-potassium chloride and water-magnesium chloride systems were measured using DSC in this study. The plots of liquidus temperatures as a function of composition show good agreement with partially available literature data. The measured eutectic temperatures of water-potassium chloride and water-magnesium chloride mixtures are -11.1℃ and -33.2℃, respectively. The heating curve of the eutectic mixture of water-potassium chloride was also used to confirm the eutectic temperature. The eutectic compositions of water-potassium chloride and water-magnesium chloride systems are 19.5 wt% KCI and 21.6 wt% MgCl2, respectively. The eutectic composition of water-potassium chloride was also estimated from the eutectic fraction data. In comparison with the available literature data, the DSC measurement and the eutectic fractional transformation methods provide consistent and accurate results. The solid state heat capacity data of the nearly eutectic binary mixtures were also evaluated from the measured DSC data. |
本系統中英文摘要資訊取自各篇刊載內容。