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| 題 名 | Preparation and Reactivity of Mo(NCMe)(η[feb4]-C[feaf]Ph[feaf])[feaf](η[fed5]-C[feb2]Ph[feb2]) |
|---|---|
| 作 者 | 張淑琴; 葉文彥; 李錦祥; 彭旭明; | 書刊名 | Journal of the Chinese Chemical Society |
| 卷 期 | 49:3 2002.06[民91.06] |
| 頁 次 | 頁325-330 |
| 分類號 | 346.01 |
| 關鍵詞 | Molybdenum; Molybdenocene; Alkyne coupling; Cyclobutadiene complexes; |
| 語 文 | 英文(English) |
| 英文摘要 | Reaction of Mo(CO) (η□-C□Ph□)□(η□-C□Ph□) and Me□NO in acetonitrile solvent affords Mo(NcMe)(η□-C□Ph□)□(η□-C□Ph□) 1.Compound 1 reacts with trimethylphosphine to produce Mo(PMe□)(η□-C□Ph□)□(η□-C□Ph□)2, or reacts with diphenylacetylene to produce (η□-C□Ph□)□Mo 3 and MO(η□-O□CPh)(η□-C□Ph□ H)(η□-C□Ph□) 4.The molecular structures of 1, 2 and 4 have been determined by an X-ray diffraction study. |
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